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In contrast, another study demonstrated that melatonin could inhibit TSH secretion and directly inhibit the secretion of T4 [89]

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There is only the case of the nuclear transcription factor c-Jun that, due to an unusual redox potential, could react with GSSG at relatively high ratio of GSH/GSSG = 13 ( S -glutathionylation within the cells involves reaction of the “critical cysteine” on protein or GSH with a corresponding oxidized derivative such as S-nitrosyl ( S -NO), sulfenic acid ( S -OH), thiyl radical ( S )